Revealing the Ion Chemistry Occurring in High Kinetic Energy-Ion Mobility Spectrometry: A Proof of Principle Study
نویسندگان
چکیده
Here, we present proof of principle studies to demonstrate how the product ions associated with ion mobility peaks obtained from a High Kinetic Energy-Ion Mobility Spectrometer (HiKE-IMS) measurement volatile can be identified using Proton Transfer Reaction/Selective Reagent Ion-Time-of-Flight-Mass (PTR/SRI-ToF-MS) when operating both instruments at same reduced electric field value and similar humidities. This identification improves our understanding chemistry occurring in source region HiKE-IMS. The combination two analytical techniques is needed, because HiKE-IMS three reagent (NO+, H3O+ O2+•) are time high concentrations reaction instrument for fields 100 Td above. means that even mass spectrometer coupled HiKE-IMS, assignment given level confidence challenging. In this paper, an alternative approach PTR/SRI-ToF-MS allows separate investigations reactions NO+, O2+•. study, apply four nitrile containing organic compounds, namely acetonitrile, 2-furonitrile, benzonitrile acrylonitrile. Both were operated commonly used strength 120 gas flows
منابع مشابه
DETECTION AND MEASUREMENT OF ACETONE IN THE BREATH OF DIABETICS BY ION MOBILITY SPECTROMETRY METHOD
Background: The ion mobility spectrometry (IMS) is an analytical technique that is widely used due to its high sensitivity and speed for the detection of ionized molecules in gas phase and under atmospheric pressure. Breath analysis is a new method for obtaining information about person's clinical conditions that is considered by researchers. Human exhaled air contains a variety of components s...
متن کاملHigh-resolution ion cyclotron mobility spectrometry.
A novel ion mobility spectrometry instrument incorporating a cyclotron geometry drift tube is presented. The drift tube consists of eight regions, four curved drift tubes and four ion funnels. Packets of ions are propagated around the drift tube by changing the drift field at a frequency that is resonant with the ion's drift time through each region. The approach trims each packet of ions as it...
متن کاملIon Mobility Mass Spectrometry
for more complex analysers for automated sample processing and plant control. The separation time will continue to decrease; in the past there has been limited interest in fast separations but this could change as automated sample processing is developed. Increasing use of coupled techniques such as GC-GC, liquid chromatography-GC, and supercritical Suid chromatography-GC for the separation of ...
متن کاملfocus on communication in iranian high school language classes: a study of the role of teaching materials in changing the focus onto communication in language classes
چکیده ارتباط در کلاس به عوامل زیادی از جمله معلمان، دانش آموزان، برنامه های درسی و از همه مهم تر، مواد آموزشی وابسته است. در تدریس ارتباطی زبان که تاکید زیادی بر توانش ارتباطی دارد، کتاب درسی به عنوان عامل موثر بر پویایی کلاس محسوب میگردد که درس ها را از طریق فراهم آوردن متن ارتباط کلاسی و هم چنین نوع تمرین زبانی که دانش آموزان در طول فعالیت های کلاسی به آن مشغول اند، کنترل می کند. این حقیقت ک...
15 صفحه اولذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Analytica
سال: 2023
ISSN: ['2673-4532']
DOI: https://doi.org/10.3390/analytica4020010