Revealing the Ion Chemistry Occurring in High Kinetic Energy-Ion Mobility Spectrometry: A Proof of Principle Study

نویسندگان

چکیده

Here, we present proof of principle studies to demonstrate how the product ions associated with ion mobility peaks obtained from a High Kinetic Energy-Ion Mobility Spectrometer (HiKE-IMS) measurement volatile can be identified using Proton Transfer Reaction/Selective Reagent Ion-Time-of-Flight-Mass (PTR/SRI-ToF-MS) when operating both instruments at same reduced electric field value and similar humidities. This identification improves our understanding chemistry occurring in source region HiKE-IMS. The combination two analytical techniques is needed, because HiKE-IMS three reagent (NO+, H3O+ O2+•) are time high concentrations reaction instrument for fields 100 Td above. means that even mass spectrometer coupled HiKE-IMS, assignment given level confidence challenging. In this paper, an alternative approach PTR/SRI-ToF-MS allows separate investigations reactions NO+, O2+•. study, apply four nitrile containing organic compounds, namely acetonitrile, 2-furonitrile, benzonitrile acrylonitrile. Both were operated commonly used strength 120 gas flows

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ژورنال

عنوان ژورنال: Analytica

سال: 2023

ISSN: ['2673-4532']

DOI: https://doi.org/10.3390/analytica4020010